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|Section2= |Section7= |Section8= }} Phenylazide is an organic compound with the formula C6H5N3. It is one of the prototypical organic azides. It has a pungent odor. The structure consists of a linear azide substituent bound to a phenyl group. The C-N=N angle is approximately 120°. ==Preparation== Phenyl azide is prepared by the diazotization of phenylhydrazine with nitrous acid: :C6H5NHNH2 + HNO2 → C6H5N3 + 2 H2O Aryl iodides bearing electron-withdrawing substituents undergo metathesis with sodium azide in the presence of Cu(I), sodium ascorbate, and N,N'-dimethylethane-1,2-diamine (DMEA): :RC6H4I + NaN3 → RC6H4N3 + NaI 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「phenyl azide」の詳細全文を読む スポンサード リンク
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